For many li-ion laptop batteries, the manufacturer’s configuration of a 100 % charge is pretty much equivalent to overcharging. I’ve seen many laptops over the years with swollen batteries, almost all of them had been plugged in all the time, with the battery kept at 100 % charge.
As an electrical engineer you should know that technically there is no 100 % charge for batteries. A battery can more or less safely be charged up to to a certain voltage. The 100 % charge point is something the manufacturer can choose (of course within limits depending on cell chemistry). A manufacturer can choose a higher cell voltage than another to gain a little more capacity, at the cost of longterm reliability. There are manufacturers that choose a cell voltage of 4250 mV and while that’s possible and works okay if charged only occasionally, if plugged in all the time, this pretty much ensures killing the batteries rather quickly. I would certainly call that overcharging.
Since you already mentioned charging thresholds, I just want to say, anyone considering using a laptop as a server should absolutely make use of this feature and limit the maximum charge.
Lots of answers about use-cases of additional wifi networks, so I won’t go into that. I haven’t seen the downsides mentioned here, though. While technically you can run lots of wifi networks of off the same wifi router/ap, each SSID takes a bit of air time to broadcast. While this might sound rather insignificant since this is only a rather tiny bit of information transmitted, it is actually more significant than one might expect. For one the SSIDs are broadcast quite often, but also they are always transmitted at the lowest possible speed (meaning they require a lot more airtime than normal WiFi traffic would require for the same amount of data) for compatibility reasons. This is also the reason why it is a good idea to disable older wifi standards if not needed by legacy clients (such as 54 Mbit/s 802.11G wifi).
Having two networks is usually fine and doesn’t cause noticable performance degradation, having 4 or more networks is usually noticable, particularily in an already crowded area with lots of wifi networks.